Open AccessPolyoxometalates: [Ln 6 O 8 ] Cluster‐Encapsulating Polyplumbites as New Polyoxometalate Members and Record Inorganic Anion‐Exchange Materials for ReO 4 − Sequestration (Adv. Sci. 17/2019)
Author(s) -
Lin Jian,
Zhu Lin,
Yue Zenghui,
Yang Chuang,
Liu Wei,
AlbrechtSchmitt Thomas E.,
Wang JianQiang,
Wang Shuao
Publication year - 2019
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201970105
Subject(s) - polyoxometalate , sorption , adsorption , cluster (spacecraft) , ion exchange , chemistry , chemical engineering , inorganic chemistry , ion , catalysis , organic chemistry , computer science , engineering , programming language
In article number 1900381, Jian‐Qiang Wang, Shuao Wang, and co‐workers develop a family of [Ln 6 O 8 ]‐encapsulating polyplumbite clusters with highest adsorption capabilities toward ReO 4 − among all inorganic materials, representing a new family of polyoxometalates based on Group 14 elements with application potentials in the nuclear fuel cycle and overcoming the critical drawbacks of low sorption capacity and poor selectivity for traditional inorganic anion‐exchange materials toward ReO 4 − /TcO 4 − sequestration.