Metallization: New Metallic Ordered Phase of Perovskite CsPbI 3  under Pressure (Adv. Sci. 14/2019) | Zendy

Liang Yongfu | Zendy; Huang Xiaoli | Zendy; Huang Yanping | Zendy; Wang Xin | Zendy; Li Fangfei | Zendy; Wang Youchun | Zendy; Tian Fubo | Zendy; Liu Bingbing | Zendy; Shen Ze Xiang | Zendy; Cui Tian | Zendy

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Metallization: New Metallic Ordered Phase of Perovskite CsPbI 3 under Pressure (Adv. Sci. 14/2019)

Author(s) -

Liang Yongfu,

Huang Xiaoli,

Huang Yanping,

Wang Xin,

Li Fangfei,

Wang Youchun,

Tian Fubo,

Liu Bingbing,

Shen Ze Xiang,

Cui Tian

Publication year - 2019

Publication title -

advanced science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.388

H-Index - 100

ISSN - 2198-3844

DOI - 10.1002/advs.201970083

Subject(s) - perovskite (structure) , materials science , metal , atomic orbital , phase (matter) , diamond anvil cell , crystallography , metallic bonding , high pressure , condensed matter physics , chemistry , electron , metallurgy , thermodynamics , physics , organic chemistry , quantum mechanics

In article number 1900399, Xiaoli Huang, Fubo Tian, Tian Cui, and co‐workers track the bandgap evolution of perovskite CsPbI 3 under pressure by a diamond anvil cell (DAC) device. The application of pressure reduces interatomic distances and profoundly modifies electronic orbitals and bonding patterns. Finally, a new metallic ordered phase of perovskite CsPbI 3 is obtained at 39.3 GPa.

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