Open AccessCore–Shell Structured NiFeSn@NiFe (Oxy)Hydroxide Nanospheres from an Electrochemical Strategy for Electrocatalytic Oxygen Evolution Reaction
Author(s) -
Chen Mingxing,
Lu Shenglin,
Fu XianZhu,
Luo JingLi
Publication year - 2020
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201903777
Subject(s) - overpotential , tafel equation , oxygen evolution , electrocatalyst , materials science , nanoporous , electrochemistry , chemical engineering , hydroxide , alloy , nanotechnology , electrode , chemistry , metallurgy , engineering
Abstract Efficient electrocatalysts for the oxygen evolution reaction (OER) are highly desirable because of the intrinsically sluggish kinetics of OER. Herein, core–shell structured nanospheres of NiFe x Sn@NiFe (oxy)hydroxide (denoted as NiFe x Sn‐A) are prepared as active OER catalysts by a facile electrochemical strategy, which includes electrodeposition of NiFe x Sn alloy nanospheres on carbon cloth (CC) and following anodization. The alloy core of NiFe x Sn could promote charge transfer, and the amorphous shell of NiFe (oxy)hydroxide is defect‐rich and nanoporous due to the selective electrochemical etching of Sn in alkaline medium. The optimized catalyst of NiFe 0.5 Sn‐A displays a remarkable OER performance with a low overpotential of 260 mV to reach the current density of 10 mA cm −2 , a small Tafel slope of 50 mV dec −1 , a high turnover frequency of 0.194 s −1 at an overpotential of 300 mV, and a robust durability. Further characterizations indicate that the superior OER performance of the core–shell structured NiFe 0.5 Sn‐A nanospheres might originate from abundant active sites and small charge transfer resistance. This work brings a new perspective to the design and synthesis of core–shell structured nanospheres for electrocatalysis through a facile electrochemical strategy.