Open AccessMetal–Organic Framework for Transparent Electronics
Author(s) -
Wu Jie,
Chen Jinhang,
Wang Chao,
Zhou Yi,
Ba Kun,
Xu Hu,
Bao Wenzhong,
Xu Xiaohui,
Carlsson Anna,
Lazar Sorin,
Meingast Arno,
Sun Zhengzong,
Deng Hexiang
Publication year - 2020
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201903003
Subject(s) - electronics , materials science , nanotechnology , transparency (behavior) , metal organic framework , graphene , optoelectronics , epitaxy , organic electronics , conductivity , layer (electronics) , transistor , chemistry , computer science , adsorption , electrical engineering , computer security , organic chemistry , voltage , engineering
Electronics allowing for visible light to pass through are attractive, where a key challenge is to make the core functional units transparent. Here, it is shown that transparent electronics can be constructed by epitaxial growth of metal–organic frameworks (MOFs) on single‐layer graphene (SLG) to give a desirable transparency of 95.7% to 550 nm visible light and an electrical conductivity of 4.0 × 10 4 S m −1 . Through lattice and symmetry match, collective alignment of MOF pores and dense packing of MOFs vertically on SLG are achieved, as directly visualized by electron microscopy. These MOF‐on‐SLG constructs are capable of room‐temperature recognition of gas molecules at the ppb level with a linear range from 10 to 10 8 ppb, providing real‐time gas monitoring function in transparent electronics. The corresponding devices can be fabricated on flexible substrates with large size, 3 × 5 cm, and afford continuous folding for more than 200 times without losing conductivity or transparency.