Open AccessNanoscaled Lithium Powders with Protection of Ionic Liquid for Highly Stable Rechargeable Lithium Metal Batteries
Author(s) -
Pu Kaichao,
Qu Xiaolei,
Zhang Xin,
Hu Jianjiang,
Gu Changdong,
Wu Yongjun,
Gao Mingxia,
Pan Hongge,
Liu Yongfeng
Publication year - 2019
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201901776
Subject(s) - lithium (medication) , materials science , anode , overpotential , electrochemistry , lithium metal , metal , chemical engineering , fabrication , nanotechnology , inorganic chemistry , chemistry , metallurgy , electrode , medicine , alternative medicine , engineering , pathology , endocrinology
To suppress the dendrite formation and alleviate volume expansion upon striping/platting is a key challenge for developing practical lithium metal anodes. Lithium metal in powder form possesses great potential to address this issue due to large specific surface area. However, the fabrication of powdery metallic lithium is largely restricted because of its unique softness, stickiness, and high reactivity. Here, a safe and readily accessible cryomilling process toward lithium powders is reported. Nanoscaled lithium powders (<500 nm) are successfully prepared from lithium foils with the assistance of a high‐melting‐point ionic liquid under cryogenic temperature. The prepared lithium powder anode exhibits superior electrochemical properties in symmetric cells, including extraordinarily low yet stable overpotential (≈50 mV), ultrahigh area capacity (30 mAh cm −2 ), and good long‐term cyclability (1200 h) even cycling at high current density (10 mA cm −2 ). The powdery form of lithium also functions as a favorable prelithiation reagent for lithium‐free anodes (e.g., Si, SiO, and SnO 2 ). The findings open up a new avenue for the real‐world application of lithium metal anodes for next‐generation lithium batteries.