Open AccessFlash‐Induced Stretchable Cu Conductor via Multiscale‐Interfacial Couplings
Author(s) -
Park Jung Hwan,
Seo Jeongmin,
Kim Cheolgyu,
Joe Daniel J.,
Lee Han Eol,
Im Tae Hong,
Seok Jae Young,
Jeong Chang Kyu,
Ma Boo Soo,
Park Hyung Kun,
Kim TaekSoo,
Lee Keon Jae
Publication year - 2018
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201801146
Subject(s) - materials science , microscale chemistry , conductor , electrical conductor , elastomer , composite material , stretchable electronics , millisecond , conductivity , nanoscopic scale , flash (photography) , stress (linguistics) , substrate (aquarium) , nanoparticle , polymer , nanotechnology , optoelectronics , optics , electronics , linguistics , chemistry , mathematics education , mathematics , physics , philosophy , oceanography , astronomy , geology
Abstract Herein, a novel stretchable Cu conductor with excellent conductivity and stretchability is reported via the flash‐induced multiscale tuning of Cu and an elastomer interface. Microscale randomly wrinkled Cu (amplitude of ≈5 µm and wavelength of ≈45 µm) is formed on a polymer substrate through a single pulse of a millisecond flash light, enabling the elongation of Cu to exceed 20% regardless of the stretching direction. The nanoscale interlocked interface between the Cu nanoparticles (NPs) and the elastomer increases the adhesion force of Cu, which contributes to a significant improvement of the Cu stability and stretchability under harsh yielding stress. Simultaneously, the flash‐induced photoreduction of CuO NPs and subsequent Cu NP welding lead to outstanding conductivity (≈37 kS cm −1 ) of the buckled elastic electrode. The 3D structure of randomly wrinkled Cu is modeled by finite element analysis simulations to show that the flash‐activated stretchable Cu conductors can endure strain over 20% in all directions. Finally, the wrinkled Cu is utilized for wireless near‐field communication on the skin of human wrist.