Open AccessAn Alternative Host Material for Long‐Lifespan Blue Organic Light‐Emitting Diodes Using Thermally Activated Delayed Fluorescence
Author(s) -
Ihn SooGhang,
Lee Namheon,
Jeon Soon Ok,
Sim Myungsun,
Kang Hosuk,
Jung Yongsik,
Huh Dal Ho,
Son Young Mok,
Lee Sae Youn,
Numata Masaki,
Miyazaki Hiroshi,
GómezBombarelli Rafael,
AguileraIparraguirre Jorge,
Hirzel Timothy,
AspuruGuzik Alán,
Kim Sunghan,
Lee Sangyoon
Publication year - 2017
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201600502
Subject(s) - oled , fluorescence , optoelectronics , quantum efficiency , materials science , brightness , diode , host (biology) , nanotechnology , optics , physics , ecology , layer (electronics) , biology
It has been challenging to find stable blue organic light emitting diodes (OLEDs) that rely on thermally activated delayed fluorescence (TADF). Lack of stable host materials well‐fitted to the TADF emitters is one of the critical reasons. The most popular host for blue TADF, bis[2‐(diphenylphosphino)phenyl] ether oxide (DPEPO), leads to unrealistically high maximum external quantum efficiency. DPEPO is however an unstable material and has a poor charge transporting ability, which in turn induces an intrinsic short OLED operating lifespan. Here, an alternative host material is introduced which educes the potential efficiency and device lifespan of given TADF emitters with the appropriateness of replacing the most popular host material, DPEPO, in developing blue TADF emitters. It simultaneously provides much longer device lifespan and higher external quantum efficiency at a practical brightness due to its high material stability and electron‐transport‐type character well‐fitted for hole‐transport‐type TADF emitters.