Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd 4  Hybridization | Zendy

Yang Jianhui | Zendy; Zhang Qiuju | Zendy; Chen Liang | Zendy; Wang Gang | Zendy; Chen Xiaolong | Zendy

Open Access

Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd 4 Hybridization

Author(s) -

Yang Jianhui,

Zhang Qiuju,

Chen Liang,

Wang Gang,

Chen Xiaolong

Publication year - 2016

Publication title -

advanced science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.388

H-Index - 100

ISSN - 2198-3844

DOI - 10.1002/advs.201500314

Subject(s) - transition metal , group (periodic table) , crystallography , materials science , chemistry , organic chemistry , catalysis

A quasi‐sd 4 hybridization state for group VIIIB and IB face‐centered cubic (FCC) transition metals in low‐dimensional nanostructures is identified, in contrast to the sd 5 hybridization state in bulk. For Au, a novel three‐shelled nanowire is designed with a hexagonal close‐packed core in the sd 5 hybridization, wrapped by FCC‐(111) shell that adopts the quasi‐sd 4 hybridization. This new nanostructure exhibits remarkable stability and electronic properties.

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