Open AccessThe First Example of Hetero‐Triple‐Walled Metal–Organic Frameworks with High Chemical Stability Constructed via Flexible Integration of Mixed Molecular Building Blocks
Author(s) -
Tian Dan,
Xu Jian,
Xie ZhaoJun,
Yao ZhaoQuan,
Fu DengLin,
Zhou Zhen,
Bu XianHe
Publication year - 2016
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201500283
Subject(s) - metal organic framework , nanotechnology , materials science , structural complexity , supramolecular chemistry , block (permutation group theory) , computer science , molecule , chemistry , mathematics , organic chemistry , adsorption , geometry , artificial intelligence
An unprecedented 3D hetero‐triple‐walled metal‐organic framework is obtained by straightforward elaboration of the mixed molecular building block (MBB) strategy. In this approach, multiple individual flexible and rigid MBBs are integrated into one composite building block as separate layers, which are of the same shape but different sizes. This MOF shows exceptional water stability and the application of Li‐ion battery electrodes.