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A Tetraperylene Diimides Based 3D Nonfullerene Acceptor for Efficient Organic Photovoltaics
Author(s) -
Liu ShiYong,
Wu ChenHao,
Li ChangZhi,
Liu ShengQiang,
Wei KungHwa,
Chen HongZheng,
Jen Alex K.Y.
Publication year - 2015
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201500014
Subject(s) - perylene , diimide , organic solar cell , materials science , acceptor , electron acceptor , fullerene , photochemistry , chemistry , molecule , organic chemistry , physics , polymer , condensed matter physics , composite material
A nonfullerene acceptor based on a 3D tetraperylene diimide is developed for bulk heterojunction organic photovoltaics. The disruption of perylene diimide planarity with a 3D framework suppresses the self‐aggregation of perylene diimide and inhibits excimer formation. From planar monoperylene diimide to 3D tetraperylene diimide, a significant improvement of power conversion efficiency from 0.63% to 3.54% can be achieved.