Open AccessA Temperature‐Responsive Smart Europium Metal‐Organic Framework Switch for Reversible Capture and Release of Intrinsic Eu 3+ Ions
Author(s) -
Zhu Min,
Song XueZhi,
Song ShuYan,
Zhao ShuNa,
Meng Xing,
Wu LanLan,
Wang Cheng,
Zhang HongJie
Publication year - 2015
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.201500012
Subject(s) - europium , carboxylate , materials science , ion , metal organic framework , smart material , ligand (biochemistry) , covalent bond , nanotechnology , crystallography , chemistry , stereochemistry , organic chemistry , biochemistry , receptor , adsorption
Stimuli‐responsive structural transformations are emerging as a scaffold to develop a charming class of smart materials. A EuL metal‐organic framework (MOF) undergoes a reversible temperature‐stimulated single‐crystal to single‐crystal transformation, showing a specific behavior of fast capture/release of free Eu 3+ in the channels at low and room temperatures. At room temperature, compound 1a is obtained with one free carboxylate group severing as further hook, featuring one‐dimensional square channels filled with intrinsic free europium ions. Trigged by lowering the ambient temperature, 1b is gained. In 1b , the intrinsic free europium ions can be fast captured by the carboxylate‐hooks anchored in the framework, resulting in the structural change and its channel distortion. To the best of our knowledge, this is the first report of such a rapid and reversible switch stemming from dynamic control between noncovalent and covalent Eu–ligand interactions. Utilizing EuL MOF to detect highly explosive 2,4,6‐trinitrophenol at room temperature and low temperature provides a glimpse into the potential of this material in fluorescence sensors.