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Improving the Performance of Paper Supercapacitors Using Redox Molecules from Plants
Author(s) -
Edberg Jesper,
Brooke Robert,
Granberg Hjalmar,
Engquist Isak,
Berggren Magnus
Publication year - 2019
Publication title -
advanced sustainable systems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.499
H-Index - 24
ISSN - 2366-7486
DOI - 10.1002/adsu.201900050
Subject(s) - supercapacitor , nanocellulose , materials science , conductive polymer , pedot:pss , capacitance , polymer , nanotechnology , energy storage , electrode , chemical engineering , chemistry , organic chemistry , composite material , cellulose , engineering , power (physics) , physics , quantum mechanics
A supercapacitor made from organic and nature‐based materials, such as conductive polymers (PEDOT:PSS), nanocellulose, and an the organic dye molecule ( alizarin ), is demonstrated. The dye molecule, which historically was extracted from the roots of the plant rubia tinctorum , is here responsible for the improvement in energy storage capacity, while the conductive polymer provides bulk charge transport within the composite electrode. The forest‐based nanocellulose component provides a mechanically strong and nonporous network onto which the conductive polymer self‐organizes. The electrical and electrochemical properties of the material composition are investigated and prototype redox‐enhanced supercapacitor devices with excellent specific capacitance exceeding 400 F g −1 and an operational stability over >1000 cycles are demonstrated. This new class of supercapacitors, which in part are based on organic materials from plants, represents an important step toward a green and sustainable energy technology.