Visible‐Light‐Mediated Aerobic Oxidative C( sp   3  )−C( sp   3  ) Bond Cleavage of Morpholine Derivatives Using 4CzIPN as a Photocatalyst | Zendy

Dong ChunLin | Zendy; Huang LanQian | Zendy; Guan Zhi | Zendy; Huang ChuSheng | Zendy; He YanHong | Zendy

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Visible‐Light‐Mediated Aerobic Oxidative C( sp 3 )−C( sp 3 ) Bond Cleavage of Morpholine Derivatives Using 4CzIPN as a Photocatalyst

Author(s) -

Dong ChunLin,

Huang LanQian,

Guan Zhi,

Huang ChuSheng,

He YanHong

Publication year - 2021

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202100455

Subject(s) - chemistry , morpholine , oxidative cleavage , bond cleavage , photochemistry , cleavage (geology) , selectivity , visible spectrum , oxidative phosphorylation , metal , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , physics , geotechnical engineering , optoelectronics , fracture (geology) , engineering

Herein, a metal‐free strategy for the aerobic oxidative cleavage of the inert C( sp 3 )−C( sp 3 ) bond was developed. Deconstruction of morpholine derivatives was conducted using visible light as an energy source and O 2 as an oxidant under mild conditions. This procedure demonstrated suitable selectivity and functional group tolerance. Moreover, a possible mechanism involving a radical process was proposed based on a series of mechanism exploration and control experiments.

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