Premium
Stereoselective Preparation of C ‐Aryl Glycosides via Visible‐Light‐Induced Nickel‐Catalyzed Reductive Cross‐Coupling of Glycosyl Chlorides and Aryl Bromides
Author(s) -
Mou ZeDong,
Wang JiaXi,
Zhang Xia,
Niu Dawen
Publication year - 2021
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202100343
Subject(s) - chemistry , aryl , glycosyl , stereoselectivity , nickel , catalysis , coupling reaction , glycoside , organic chemistry , stereochemistry , combinatorial chemistry , alkyl
A nickel‐catalyzed cross‐coupling reaction of glycosyl chlorides with aryl bromides has been developed. The reaction proceeds smoothly under visible‐light irradiation and features the use of bench‐stable glycosyl chlorides, allowing the highly stereoselective synthesis of C ‐aryl glycosides.