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Inter‐Element Boration Reactions of Carbon‐Carbon Multiple Bonds via Lewis‐Basic Activation of Boron Reagents
Author(s) -
Hirano Keiichi,
Uchiyama Masanobu
Publication year - 2021
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202001610
Subject(s) - chemistry , boron , reagent , reactivity (psychology) , main group element , carbon fibers , lewis acids and bases , electrophile , electron deficiency , photochemistry , combinatorial chemistry , organic chemistry , transition metal , catalysis , medicine , materials science , alternative medicine , pathology , composite number , composite material
Here, we review recent progress in transition‐metal‐free inter‐element boration reactions via Lewis‐basic activation of various boron reagents, focusing mainly on the boration reactions of carbon‐carbon multiple bonds without an electron‐withdrawing (activating) group and those with an electron‐withdrawing group where the polarity of the addition reaction is inverse to the “natural” reactivity.