Catalyst and Additive‐Free Selective Ring‐Opening Selenocyanation of Heterocycles with Elemental Selenium and TMSCN | Zendy

Lu LiGuo | Zendy; Bi Kang | Zendy; Huang XiaoBo | Zendy; Liu MiaoChang | Zendy; Zhou YunBing | Zendy; Wu HuaYue | Zendy

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Catalyst and Additive‐Free Selective Ring‐Opening Selenocyanation of Heterocycles with Elemental Selenium and TMSCN

Author(s) -

Lu LiGuo,

Bi Kang,

Huang XiaoBo,

Liu MiaoChang,

Zhou YunBing,

Wu HuaYue

Publication year - 2021

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202001423

Subject(s) - chemistry , reagent , selenium , ring (chemistry) , catalysis , organic chemistry , elemental analysis , ammonium , combinatorial chemistry

A catalyst and additive‐free strategy for selective ring‐opening selenocyanation of saturated heterocycles with elemental selenium and TMSCN is developed, affording a series of aliphatic selenocyanates and selenaheterocycles. In the case of unprotected unstrained N‐heterocycles, the reactions offer ammonium selenonitriles that prove to be an efficient selenonitrile reagent.

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