Front Cover Picture: Copper‐Catalyzed Synthesis of α‐Trifluoromethylacrylates from Trifluoroborylacrylates  via  Stereoretentive Radical Trifluoromethylation (Adv. Synth. Catal. 2/2021) | Zendy

Jos Swetha | Zendy; Santos Webster L. | Zendy

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Front Cover Picture: Copper‐Catalyzed Synthesis of α‐Trifluoromethylacrylates from Trifluoroborylacrylates via Stereoretentive Radical Trifluoromethylation (Adv. Synth. Catal. 2/2021)

Author(s) -

Jos Swetha,

Santos Webster L.

Publication year - 2021

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202001420

Subject(s) - chemistry , trifluoromethylation , front cover , reagent , copper , cover (algebra) , catalysis , trifluoromethyl , medicinal chemistry , polymer chemistry , organic chemistry , mechanical engineering , alkyl , engineering

The front cover picture illustrates the transformation of α‐trifluoroborylacrylates to α‐trifluoromethylacrylates using inexpensive reagents such as NaSO 2 CF 3 and TBHP at room temperature. The copper‐catalyzed reaction generates trifluoromethyl radical that is installed in a stereoretentive fashion. Details can be found in the communication by Swetha Jos and Webster L. Santos. Cover art credit: Carter J. Gottschalk (S. Jos, W. L. Santos, Adv. Synth. Catal . 2021 , 363 , 425–430; DOI: 10.1002/adsc.202000937).

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