Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination | Zendy

Xu Nuo | Zendy; Xu Jianeng | Zendy; Zhu Qing | Zendy; Liu Chao | Zendy

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Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination

Author(s) -

Xu Nuo,

Xu Jianeng,

Zhu Qing,

Liu Chao

Publication year - 2021

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202001351

Subject(s) - chemistry , bifunctional , electrophile , combinatorial chemistry , stereoselectivity , organic chemistry , catalysis

A method for the synthesis of allylboronates via Zweifel‐type deprotonative olefination was demonstrated. Tetrasubstituted vinylboronates were used as the substrates. NCS ( N ‐chlorosuccinimide) was used as a bifunctional additive, electrophile and base. This method exhibited a different elimination strategy in Zweifel type transformation to afford allylboronates. The homo‐alcohols and alkenes were stereoselective synthesized from the obtained allylboronates, demonstrating the synthetic value of this methodology.

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