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Modular Tandem Mizoroki‐Heck/Reductive Heck Reactions to Construct Fluorenes from Cyclic Diaryliodoniums
Author(s) -
Peng Xiaopeng,
Yang Yang,
Luo Bingling,
Wen Shijun,
Huang Peng
Publication year - 2021
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202001080
Subject(s) - chemistry , heck reaction , fluorene , tandem , scope (computer science) , palladium , combinatorial chemistry , catalysis , modular design , organic chemistry , materials science , composite material , polymer , operating system , computer science , programming language
Starting from cyclic diaryliodoniums and terminal alkenes, a diverse set of fluorenes is conveniently constructed. The reactions catalyzed by palladium undergo one conventional Mizoroki‐Heck reaction and one reductive Heck reaction. The scope of alkenes is general, leading to 29 fluorenes which would expand the structural diversity of fluorene reservoir.