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Photochemical O−H Functionalization Reactions of Cyclic Diazoamides
Author(s) -
Empel Claire,
Verspeek Dennis,
Jana Sripati,
Koenigs Rene M.
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202000818
Subject(s) - chemistry , surface modification , carbene , photochemistry , yield (engineering) , ether , organic chemistry , catalysis , materials science , metallurgy
Herein, we describe the photochemical O−H functionalization reaction of acidic alcohols with cyclic diazoamides. We studied the O−H functionalization reaction of different fluorinated and non‐fluorinated alcohols to give the corresponding ether products in high yields (43 examples, up to 97% yield). Furthermore, we performed studies to evaluate a photoexcited proton transfer reaction pathway in comparison to classic carbene transfer reactions.
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