A Gold(I)‐Catalyzed Tandem Cyclization to Benzo[ b ]indeno[1,2‐ e ][1,4]diazepines from  o ‐Phenylenediamines and Ynones | Zendy

Xie Fukai | Zendy; Zhang Bo | Zendy; Chen Yanyu | Zendy; Jia Hongwei | Zendy; Sun Lei | Zendy; Zhuang Kaitong | Zendy; Yin Lili | Zendy; Cheng Maosheng | Zendy; Lin Bin | Zendy; Liu Yongxiang | Zendy

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A Gold(I)‐Catalyzed Tandem Cyclization to Benzo[ b ]indeno[1,2‐ e ][1,4]diazepines from o ‐Phenylenediamines and Ynones

Author(s) -

Xie Fukai,

Zhang Bo,

Chen Yanyu,

Jia Hongwei,

Sun Lei,

Zhuang Kaitong,

Yin Lili,

Cheng Maosheng,

Lin Bin,

Liu Yongxiang

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000755

Subject(s) - chemistry , tandem , diazepine , catalysis , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , ring (chemistry) , materials science , composite material

A gold‐catalyzed tandem cyclization of o ‐phenylenediamines with ynones to synthesize benzo[ b ]indeno[1,2‐ e ][1,4]diazepine has been developed. The mechanism was explored by control experiments. The method provides a way to access a range of benzo[ b ]indeno[1,2‐ e ][1,4]diazepine derivatives in diversity‐oriented synthesis aiming at discovering structurally diverse scaffolds.

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