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Visible‐Light‐Enabled Multicomponent Cascade Transformation from Indoles to 2‐Azidoindolin‐3‐yl 2‐Aminobenzoates
Author(s) -
Zhang LingLing,
Xu MengMeng,
Cao WenBin,
Xu XiaoPing,
Ji ShunJun
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202000637
Subject(s) - chemistry , cascade , cascade reaction , transformation (genetics) , ring (chemistry) , azide , trimethylsilyl azide , combinatorial chemistry , stereochemistry , oxygen , organic chemistry , catalysis , biochemistry , chromatography , gene
The synthesis of 2‐azido‐1‐benzoylindolin‐3‐yl 2‐benzamidobenzoate commencing from (1 H ‐indol‐1‐yl)(phenyl)methanone and trimethylsilyl azide (TMSN 3 ) under oxygen atmosphere is described in this paper. This transformation proceeds via a sequential dearomatization and ring‐opening cascade reaction of indoles in a cascade manner.