Visible‐Light‐Enabled Multicomponent Cascade Transformation from Indoles to 2‐Azidoindolin‐3‐yl 2‐Aminobenzoates | Zendy

Zhang LingLing | Zendy; Xu MengMeng | Zendy; Cao WenBin | Zendy; Xu XiaoPing | Zendy; Ji ShunJun | Zendy

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Visible‐Light‐Enabled Multicomponent Cascade Transformation from Indoles to 2‐Azidoindolin‐3‐yl 2‐Aminobenzoates

Author(s) -

Zhang LingLing,

Xu MengMeng,

Cao WenBin,

Xu XiaoPing,

Ji ShunJun

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000637

Subject(s) - chemistry , cascade , cascade reaction , transformation (genetics) , ring (chemistry) , azide , trimethylsilyl azide , combinatorial chemistry , stereochemistry , oxygen , organic chemistry , catalysis , biochemistry , chromatography , gene

The synthesis of 2‐azido‐1‐benzoylindolin‐3‐yl 2‐benzamidobenzoate commencing from (1 H ‐indol‐1‐yl)(phenyl)methanone and trimethylsilyl azide (TMSN 3 ) under oxygen atmosphere is described in this paper. This transformation proceeds via a sequential dearomatization and ring‐opening cascade reaction of indoles in a cascade manner.

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