Electron Transfer Photoredox Catalysis: Development of a Photoactivated Reductive Desulfonylation of an Aza‐Heteroaromatic Ring | Zendy

Liu YuXiu | Zendy; Song HongJian | Zendy; Wang QingMin | Zendy

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Electron Transfer Photoredox Catalysis: Development of a Photoactivated Reductive Desulfonylation of an Aza‐Heteroaromatic Ring

Author(s) -

Liu YuXiu,

Song HongJian,

Wang QingMin

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000578

Subject(s) - chemistry , ring (chemistry) , electron transfer , hydrogen atom , catalysis , photoredox catalysis , sulfonamide , substrate (aquarium) , photochemistry , molecule , photoinduced electron transfer , combinatorial chemistry , stereochemistry , organic chemistry , photocatalysis , alkyl , oceanography , geology

Herein, we report a protocol for desulfonylation of aza‐heteroaromatic rings via photoinduced electron transfer and hydrogen atom transfer. This general protocol has a wide substrate range and moderate to good yields. The utility of the method was demonstrated by the chemoselective desulfonylation of a molecule containing both an aliphatic and an aromatic sulfonamide.

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