Visible‐Light Photoredox‐Catalyzed α‐Regioselective Conjugate Addition of Allyl Groups to Activated Alkenes | Zendy

Gontala Arjun | Zendy; Woo Sang Kook | Zendy

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Visible‐Light Photoredox‐Catalyzed α‐Regioselective Conjugate Addition of Allyl Groups to Activated Alkenes

Author(s) -

Gontala Arjun,

Woo Sang Kook

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000445

Subject(s) - regioselectivity , chemistry , conjugate , allylic rearrangement , catalysis , photochemistry , photoredox catalysis , radical , adduct , alkene , visible spectrum , organic chemistry , photocatalysis , mathematical analysis , physics , mathematics , optoelectronics

The α‐regioselective conjugate addition of allyl groups to activated alkenes is a poorly explored area of research. Herein, we report an α‐adduct and ( E )‐isomer selective conjugate addition of allylsilanes to activated alkenes by visible‐light photoredox catalysis. The reaction involves allylic radicals that can be generated from allylsilanes through a photoinduced single‐electron transfer mechanism.

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