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Synthesis of Aliphatic Amides through a Photoredox Catalyzed Radical Carbonylation Involving Organosilicates as Alkyl Radical Precursors
Author(s) -
Cartier Alex,
Levernier Etienne,
Dhimane AnneLise,
Fukuyama Takahide,
Ollivier Cyril,
Ryu Ilhyong,
Fensterbank Louis
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202000314
Subject(s) - chemistry , carbonylation , alkyl , radical , catalysis , carbon monoxide , photoredox catalysis , primary (astronomy) , organic chemistry , photochemistry , medicinal chemistry , photocatalysis , physics , astronomy
Alkyl radicals, from primary to tertiary, formed by photocatalyzed oxidation of organosilicates, are involved efficiently in radical carbonylation with carbon monoxide (CO), in the presence of various amines and CCl 4 , leading to a variety of amides in moderate to good yields.