Free‐Radical‐Promoted Alkenylation of C( sp  3 )−H Bond in Chloroalkane with Cinnamic Acid and  β ‐Nitrostyrene | Zendy

Sun Minzhi | Zendy; Xu Zhengbao | Zendy; Li Wenjie | Zendy; Yang Le | Zendy; You Huichao | Zendy; Yu Dan | Zendy; Fang Fang | Zendy; Wang Yaxin | Zendy; Liu ZhongQuan | Zendy

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Free‐Radical‐Promoted Alkenylation of C( sp 3 )−H Bond in Chloroalkane with Cinnamic Acid and β ‐Nitrostyrene

Author(s) -

Sun Minzhi,

Xu Zhengbao,

Li Wenjie,

Yang Le,

You Huichao,

Yu Dan,

Fang Fang,

Wang Yaxin,

Liu ZhongQuan

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000215

Subject(s) - chemistry , cinnamic acid , double bond , halogen , free radical addition , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , alkyl

We demonstrated herein a free‐radical alkenylation of the C( sp 3 )−H bond in 1,2‐dichloroethane with cinnamic acid and β ‐nitrostyrene. This method not only provides a facile approach to chloroalkylated styrenes, but also would be instructive for halogen‐atom directing selective functionalization of inert C( sp 3 )−H bond.

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