Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles | Zendy

Wu Ju | Zendy; Guillot Régis | Zendy; Kouklovsky Cyrille | Zendy; Vincent Guillaume | Zendy

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Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles

Author(s) -

Wu Ju,

Guillot Régis,

Kouklovsky Cyrille,

Vincent Guillaume

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.202000158

Subject(s) - dihydroxylation , indole test , redox , electrochemistry , chemistry , mediator , combinatorial chemistry , hydroxylation , organic chemistry , electrode , biology , enantioselective synthesis , enzyme , catalysis , endocrinology

We describe a simple and sustainable MgBr 2 ‐mediated electrochemical dearomative dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr 2 is used in substoichiometric amount and acts as an electrolyte and potentially as a redox mediator to indirectly oxidize the indole nucleus into a bromonium ion which is involved in the aforementioned reactions.

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