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Cu‐Catalyzed Radical Selenylation of Olefin: A Direct Access to Vinyl Selenides
Author(s) -
Yang YeFei,
Li ChenYuan,
Leng Tao,
Huang XiaoBo,
Gao WenXia,
Zhou YunBing,
Liu MiaoChang,
Wu HuaYue
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.202000015
Subject(s) - chemistry , olefin fiber , selenium , catalysis , carbon fibers , double bond , polymer chemistry , combinatorial chemistry , organic chemistry , materials science , composite number , composite material
A method for the synthesis of vinyl selenides via Cu‐catalyzed three‐component reactions of arylboronic acids, Se powder and diarylethylenes has been developed. The reaction proceeds via addition of in situ generated selenium‐centered radical to carbon‐carbon double bond. This method highlights the use of easily accessible Se powder as selenium source in the construction of vinyl selenides for the first time.