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Synthesis and Application of Heterocyclic Germatranes via Rhodium‐Catalyzed Directed C−H Activation/Annulation with Alkynyl Germatranes and Palladium‐Catalyzed Cross‐Coupling
Author(s) -
Xu MengYu,
Wang Chao,
Jiang WeiTao,
Xiao Bin
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201901633
Subject(s) - chemistry , annulation , rhodium , palladium , catalysis , coupling reaction , combinatorial chemistry , organic chemistry , medicinal chemistry , stereochemistry
Rhodium‐catalyzed C−H activation and annulation with alkynyl germatranes for the synthesis of heterocyclic germatranes is described. Various heterocyclic germatranes were constructed by this protocol and applied in multiple derivatizations such as palladium‐catalyzed cross‐coupling reactions.