Three‐Component Reaction of  p ‐Quinone Monoacetals, Amines and Diarylphosphine Oxides to Afford  m‐ (Phosphinyl)anilides | Zendy

Shen Ruwei | Zendy; Wang Xin | Zendy; Zhang Shunlin | Zendy; Dong Chao | Zendy; Zhu Dunru | Zendy; Han LiBiao | Zendy

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Three‐Component Reaction of p ‐Quinone Monoacetals, Amines and Diarylphosphine Oxides to Afford m‐ (Phosphinyl)anilides

Author(s) -

Shen Ruwei,

Wang Xin,

Zhang Shunlin,

Dong Chao,

Zhu Dunru,

Han LiBiao

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201901421

Subject(s) - chemistry , quinone , nucleophile , amine gas treating , component (thermodynamics) , acetal , enone , condensation , medicinal chemistry , nucleophilic addition , photochemistry , organic chemistry , catalysis , physics , thermodynamics

The three‐component reaction of p ‐quinone monoacetals, amines and diarylphosphine oxides is developed to afford m‐ (diarylphosphinyl)anilides in moderate to high yields. The reaction may proceed via a process involving phospha‐nucleophilic addition to an iminoquinone acetal intermediate and/or carbonyl‐amine condensation with a phosphinyl enone intermediate.

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