Hypervalent Iodine(III)‐Promoted Rapid Cascade Reaction of Quinoxalinones with Unactivated Alkenes and TMSN 3 | Zendy

Shen Jiabin | Zendy; Xu Jun | Zendy; Huang Lin | Zendy; Zhu Qing | Zendy; Zhang Pengfei | Zendy

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Hypervalent Iodine(III)‐Promoted Rapid Cascade Reaction of Quinoxalinones with Unactivated Alkenes and TMSN 3

Author(s) -

Shen Jiabin,

Xu Jun,

Huang Lin,

Zhu Qing,

Zhang Pengfei

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201901314

Subject(s) - hypervalent molecule , chemistry , cascade , iodine , component (thermodynamics) , iodine compounds , combinatorial chemistry , cascade reaction , transformation (genetics) , organic chemistry , catalysis , chromatography , biochemistry , physics , gene , thermodynamics

The first example of rapidly three‐component cascade reaction of quinoxalinones with unactivated alkenes and TMSN 3 under mild condition has been described. This approach provides a practical solution for the rapid modification of quinoxalinones and enables new planning strategies for the synthesis of bioactive organoazides. A radical mechanism is responsible for this three‐component transformation.

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