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Rhodium(III)‐Catalyzed Direct C−H Alkylation of Ferrocenes with Diazo Compounds under Weakly Coordinating Approach
Author(s) -
Zhang Lulu,
Zhao Jiakai,
Mou Qi,
Teng Dawei,
Meng Xiangtai,
Sun Bo
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201901193
Subject(s) - chemistry , diazo , rhodium , alkylation , ferrocene , catalysis , combinatorial chemistry , medicinal chemistry , organic chemistry , electrochemistry , electrode
An efficient synthesis of ferrocene derivatives via rhodium(III)‐catalyzed direct C−H alkylation with diazo compounds under weakly coordinating group has been presented. This protocol provides an approach towards access to various ferrocene derivatives using carboxamides, giving alkylated ferrocenes in high yields (up to 87%).