Palladium‐Catalyzed Carboperfluoroalkylation of Alkynes with Fluoroalkyl Iodides and Arylstannanes | Zendy

Upadhyay Nitinkumar Satyadev | Zendy; Chaładaj Wojciech | Zendy

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Palladium‐Catalyzed Carboperfluoroalkylation of Alkynes with Fluoroalkyl Iodides and Arylstannanes

Author(s) -

Upadhyay Nitinkumar Satyadev,

Chaładaj Wojciech

Publication year - 2020

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201901027

Subject(s) - chemistry , stille reaction , palladium , catalysis , tandem , sequence (biology) , combinatorial chemistry , transformation (genetics) , polymer chemistry , organic chemistry , biochemistry , materials science , composite material , gene

A tandem Pd‐catalyzed carboperfluoroalkylation through a sequence of iodoperfluoroalkylation and Stille coupling is presented. This novel three‐component transformation proceeds smoothly with excellent regio‐ and stereoselectivities, giving rise to fluoroalkyl‐substituted tri‐ and tetrasubstituted olefins.

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