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Amide‐Directed Bay‐Region Two‐Step Annulative π‐Extension (APEX) of Biphenyls and Terphenyls with Diaryliodonium Salts: Efficient Access to Polycyclic Aromatic Hydrocarbons
Author(s) -
Peng Qiong,
Zhang Wen,
Zhao Ke,
Du Yu,
Feng Chun,
Wang BiQin,
Fang DongMei,
Chen XiaoZhen,
Ni HaiLiang,
Xiang ShiKai
Publication year - 2020
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201901010
Subject(s) - triphenylene , chemistry , amide , tetracene , anthracene , bay , combinatorial chemistry , organic chemistry , molecule , civil engineering , engineering
An amide‐directed bay‐region two‐step annulative π‐extension reaction of biphenyls and terphenyls with diaryliodonium salts has been developed. A variety of polycyclic aromatic hydrocarbons can be synthesized efficiently according to this approach, such as triphenylene, dibenzo[ fg,op ]tetracene, and tribenzo[ fg,ij,rst ]pentaphene derivatives.

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