Palladium‐Catalyzed Cascade Reductive and Carbonylative Cyclization of  Ortho ‐Iodo‐Tethered Methylenecyclopropanes (MCPs) Using  N ‐Formylsaccharin as CO Source | Zendy

Fan Xing | Zendy; Shi Min | Zendy; Wei Yin | Zendy

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Palladium‐Catalyzed Cascade Reductive and Carbonylative Cyclization of Ortho ‐Iodo‐Tethered Methylenecyclopropanes (MCPs) Using N ‐Formylsaccharin as CO Source

Author(s) -

Fan Xing,

Shi Min,

Wei Yin

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201901005

Subject(s) - chemistry , palladium , stereoselectivity , catalysis , cascade , reductive elimination , combinatorial chemistry , medicinal chemistry , organic chemistry , stereochemistry , chromatography

A palladium‐catalyzed reductive and carbonylative cyclization of ortho ‐iodo‐tethered methylenecyclopropanes (MCPs) using N ‐formylsaccharin as CO source has been developed, affording the desired indanone derivatives in moderate to good yields with high regio‐ and stereoselectivity and good functional group compatibility.

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