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Nickel‐Catalyzed Reaction of Aryl 2‐Pyridyl Ethers with Silylzinc Chlorides: Silylation of Aryl 2‐Pyridyl Ethers via Cleavage of the Carbon−Oxygen Bond
Author(s) -
Kong YingYing,
Wang ZhongXia
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900949
Subject(s) - silylation , chemistry , aryl , catalysis , medicinal chemistry , bond cleavage , nickel , cleavage (geology) , functional group , organic chemistry , alkyl , polymer , geotechnical engineering , fracture (geology) , engineering
Ni‐catalyzed C−O(Py) bond activation and silylation of aryl 2‐pyridyl ethers with silylzinc chlorides were carried out. This protocol allowed the 2‐pyridyloxy group to be substituted by a silyl group with short reaction times, mild reaction conditions, and good compatibility of functional groups.