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Cobalt‐Catalyzed Transfer Hydrogenation of α‐Ketoesters and N ‐Cyclicsulfonylimides Using H 2 O as Hydrogen Source
Author(s) -
Gao Yang,
Zhang Xuexin,
Laishram Ronibala Devi,
Chen Jingchao,
Li Kangkui,
Zhang Keyang,
Zeng Guangzhi,
Fan Baomin
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900636
Subject(s) - chemistry , catalysis , cobalt , transfer hydrogenation , hydrogen , ligand (biochemistry) , zinc , metal , combinatorial chemistry , medicinal chemistry , organic chemistry , ruthenium , receptor , biochemistry
A Co‐catalyzed effective transfer hydrogenation of various α‐ketoesters and N ‐cyclicsulfonylimides by safe and environmentally benign H 2 O as hydrogen source is described. The reaction used easily available and easy to handle zinc metal as a reductant. Interestingly, the catalytic system does not require ligand for reduction of N ‐cyclicsulfonylimides.