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Tandem Reactions of Ynones: via Conjugate Addition of Nitrogen‐, Carbon‐, Oxygen‐, Boron‐, Silicon‐, Phosphorus‐, and Sulfur‐Containing Nucleophiles
Author(s) -
Li Yang,
Yu Jian,
Bi Yicheng,
Yan Guobing,
Huang Dayun
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900611
Subject(s) - chemistry , nucleophile , sulfur , boron , conjugate , carbon fibers , nitrogen , phosphorus , organic chemistry , silicon , organic synthesis , oxygen , addition reaction , combinatorial chemistry , catalysis , mathematical analysis , materials science , mathematics , composite number , composite material
Ynones are widely used in organic synthesis. Their great success is rooted in their multiple functional groups. This review focus on advance of ynones in published in the decade 2009–2019. Reactions triggered by the conjugate addition of nitrogen‐, carbon‐, oxygen‐, boron‐, silicon‐, phosphorus‐, and sulfur‐containing nucleophiles are thoroughly discussed and summarized herein. Multicomponent reactions, rearrangements, cycloadditions, regio‐ and stereoselective synthesis, oxidations, coupling, green chemistry et al. are depicted in detail. We hope that this review will promote future research in this area.