Palladium‐Catalyzed Regio‐ and Stereoselective Sulfonylation of Aryl Propiolates with Sulfonyl Hydrazides: Access to ( E )‐ β ‐Aryl Sulfonyl Acrylates | Zendy

Jiang Huanfeng | Zendy; Yan Wuxin | Zendy; Huang Jiuzhong | Zendy; Tan Chaowei | Zendy; Zhan Lingzhi | Zendy; Wu Wanqing | Zendy

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Palladium‐Catalyzed Regio‐ and Stereoselective Sulfonylation of Aryl Propiolates with Sulfonyl Hydrazides: Access to ( E )‐ β ‐Aryl Sulfonyl Acrylates

Author(s) -

Jiang Huanfeng,

Yan Wuxin,

Huang Jiuzhong,

Tan Chaowei,

Zhan Lingzhi,

Wu Wanqing

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201900456

Subject(s) - sulfonyl , chemistry , aryl , stereoselectivity , palladium , catalysis , organic chemistry , combinatorial chemistry , alkyl

An efficient method for the synthesis of ( E )‐ β ‐aryl sulfonyl acrylates has been reported. This palladium‐catalyzed approach showed excellent regio‐ and stereoselectivity in the sulfonylation of aryl propiolates with sulfonyl hydrazides. Through this approach, a wide range of ( E )‐ β ‐aryl sulfonyl acrylates were obtained in moderate to high yields.

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