Premium
Palladium‐Catalyzed Regio‐ and Stereoselective Sulfonylation of Aryl Propiolates with Sulfonyl Hydrazides: Access to ( E )‐ β ‐Aryl Sulfonyl Acrylates
Author(s) -
Jiang Huanfeng,
Yan Wuxin,
Huang Jiuzhong,
Tan Chaowei,
Zhan Lingzhi,
Wu Wanqing
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900456
Subject(s) - sulfonyl , chemistry , aryl , stereoselectivity , palladium , catalysis , organic chemistry , combinatorial chemistry , alkyl
An efficient method for the synthesis of ( E )‐ β ‐aryl sulfonyl acrylates has been reported. This palladium‐catalyzed approach showed excellent regio‐ and stereoselectivity in the sulfonylation of aryl propiolates with sulfonyl hydrazides. Through this approach, a wide range of ( E )‐ β ‐aryl sulfonyl acrylates were obtained in moderate to high yields.