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Sulfur‐Catalyzed Stereo and Regioselective Synthesis of Heteropropellanes via Oxidative Condensation of Cyclohexanones with 2‐Aminophenols
Author(s) -
Nguyen Thanh Binh,
Retailleau Pascal
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900436
Subject(s) - regioselectivity , chemistry , sulfur , oxidative phosphorylation , catalysis , condensation , oxidative coupling of methane , functional group , combinatorial chemistry , organic chemistry , biochemistry , physics , polymer , thermodynamics
Sulfur was found to be an excellent catalyst for the oxidative coupling of cyclohexanones with o ‐aminophenols using DMSO as oxidant. A wide range of heteropropellanes were obtained with complete regio and stereoselectivities and functional group tolerance.