Bis(imidazolidine)pyridine‐CoCl 2 : A Novel, Catalytically Active Neutral Complex for Asymmetric Michael Reaction of 1,3‐Carbonyl Compounds with Nitroalkenes | Zendy

Arai Takayoshi | Zendy; Iimori Yuko | Zendy; Shirasugi Mayu | Zendy; Shinohara Ryota | Zendy; Takagi Yuri | Zendy; Suzuki Takumi | Zendy; Ma Junma | Zendy; Kuwano Satoru | Zendy; Masu Hyuma | Zendy

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Bis(imidazolidine)pyridine‐CoCl 2 : A Novel, Catalytically Active Neutral Complex for Asymmetric Michael Reaction of 1,3‐Carbonyl Compounds with Nitroalkenes

Author(s) -

Arai Takayoshi,

Iimori Yuko,

Shirasugi Mayu,

Shinohara Ryota,

Takagi Yuri,

Suzuki Takumi,

Ma Junma,

Kuwano Satoru,

Masu Hyuma

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201900421

Subject(s) - imidazolidine , chemistry , pyridine , michael reaction , ligand (biochemistry) , catalysis , amine gas treating , medicinal chemistry , stereochemistry , organic chemistry , receptor , biochemistry

A neutral bis(imidazolidine)pyridine (PyBidine)‐CoCl 2 complex showed catalytic activity for the Michael reaction of malonates with nitroalkenes. The results indicated that a weak amine base aided enolate formation from the neutral complex, in which the N−H proton of the imidazolidine ligand played a significant role.

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