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Lithium‐Free Synthesis of Sodium 2,2,6,6‐Tetramethylpiperidide and Its Synthetic Applications
Author(s) -
Asako Sobi,
Kodera Masato,
Nakajima Hirotaka,
Takai Kazuhiko
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900215
Subject(s) - chemistry , lithium (medication) , sodium , base (topology) , inorganic chemistry , organic chemistry , medicine , mathematical analysis , mathematics , endocrinology
Lithium‐free synthetic methods for sodium 2,2,6,6‐tetramethylpiperide (NaTMP) have been developed using sodium dispersion as a sole sodium source. The prepared NaTMP was used as a Brønsted base, that exhibited some differences in reactivities from LiTMP.