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Copper‐Catalyzed Synthesis of gem ‐Bisarylthio Enamines under Redox‐Neutral Conditions
Author(s) -
Ni Jiabin,
Mao Xiaokang,
Zhang Ao
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201900035
Subject(s) - chemistry , oxime , copper , catalysis , redox , combinatorial chemistry , coupling (piping) , organic chemistry , metallurgy , materials science
An efficient approach for the construction of gem‐bisarylthio enamines via coupling of oxime acetates with diaryl disulfides is developed. This process involved copper‐catalyzed N−O/S−S bond cleavages and formation of two new C−S bonds. A broad range of substrates with diverse functional groups were tolerated.