A Recyclable Chiral 2‐(Triphenylmethyl)pyrrolidine Organocatalyst Anchored to [60]Fullerene | Zendy

Rosso Cristian | Zendy; Emma Marco G. | Zendy; Martinelli Ada | Zendy; Lombardo Marco | Zendy; Quintavalla Arianna | Zendy; Trombini Claudio | Zendy; Syrgiannis Zois | Zendy; Prato Maurizio | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Recyclable Chiral 2‐(Triphenylmethyl)pyrrolidine Organocatalyst Anchored to [60]Fullerene

Author(s) -

Rosso Cristian,

Emma Marco G.,

Martinelli Ada,

Lombardo Marco,

Quintavalla Arianna,

Trombini Claudio,

Syrgiannis Zois,

Prato Maurizio

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201900009

Subject(s) - chemistry , pyrrolidine , enantioselective synthesis , iminium , organocatalysis , fullerene , combinatorial chemistry , organic chemistry , fullerene chemistry , catalysis

Hybridization of a chiral 3‐hydroxy‐2‐trityl‐pyrrolidine deriving from ( R )‐pyrrolidinol with [60]fullerene via click chemistry provides a highly efficient supported enantioselective organocatalyst, which was successfully exploited in a Michael addition of malonates to cinnamaldehydes, via iminium ion activation. The supported organocatalyst was recycled up to six times, with only a moderate decrease in terms of activity and with no loss in enantioselectivity.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research