Copper‐Catalyzed Sequential C( sp  2 )/C( sp  3 )−H Amination of 2‐Vinylanilines with  N ‐Fluorobenzenesulfonimide | Zendy

Cao WenBin | Zendy; Xu XiaoPing | Zendy; Ji ShunJun | Zendy

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Copper‐Catalyzed Sequential C( sp 2 )/C( sp 3 )−H Amination of 2‐Vinylanilines with N ‐Fluorobenzenesulfonimide

Author(s) -

Cao WenBin,

Xu XiaoPing,

Ji ShunJun

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201801710

Subject(s) - chemistry , amination , catalysis , intermolecular force , nitrogen , copper , substrate (aquarium) , combinatorial chemistry , medicinal chemistry , organic chemistry , molecule , oceanography , geology

An oxidative C−H diamination of 2‐vinylanilines with N ‐fluorobenzenesulfonimide (NFSI) was developed for the efficient synthesis of indole frameworks. The reaction proceeded via sequential intra‐/intermolecular diamination of C( sp 2 )−H and C( sp 3 )−H bond, incorporating one nitrogen from the substrate and the other nitrogen from the NFSI.

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