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Iodine‐Catalyzed Oxidative Rearrangement of Amines to α‐Amino Acetals and α‐Amino Aldehydes
Author(s) -
Zhou MinJie,
Zhu ShouFei,
Zhou QiLin
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201801670
Subject(s) - chemistry , oxidative phosphorylation , iodine , catalysis , amino acid , organic chemistry , combinatorial chemistry , organocatalysis , biochemistry , enantioselective synthesis
A protocol for iodine‐catalyzed oxidative rearrangement of tertiary and secondary amines has been developed. This metal‐free protocol provides an atom‐economical, efficient access to synthetically useful α‐amino acid derivatives from readily available acyclic and cyclic tertiary or secondary amines.