Chemoselectivity Switching in the Rhodium‐Catalyzed Reactions of 4‐Substituted‐1‐sulfonyl‐1,2,3‐triazoles with Allenols: Noticeable Differences between 4‐Acyl‐ and 4‐Aryl‐Triazoles | Zendy

Alcaide Benito | Zendy; Almendros Pedro | Zendy; Fernández Israel | Zendy; del Campo Teresa Martínez | Zendy; Palop Guillermo | Zendy; ToledanoPinedo Mireia | Zendy; DelgadoMartínez Patricia | Zendy

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Chemoselectivity Switching in the Rhodium‐Catalyzed Reactions of 4‐Substituted‐1‐sulfonyl‐1,2,3‐triazoles with Allenols: Noticeable Differences between 4‐Acyl‐ and 4‐Aryl‐Triazoles

Author(s) -

Alcaide Benito,

Almendros Pedro,

Fernández Israel,

del Campo Teresa Martínez,

Palop Guillermo,

ToledanoPinedo Mireia,

DelgadoMartínez Patricia

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201801424

Subject(s) - chemoselectivity , chemistry , rhodium , moiety , aryl , sulfonyl , substituent , catalysis , medicinal chemistry , organic chemistry , alkyl

Tunable chemoselectivity ( O ‐ versus C ‐attack) in the rhodium‐catalyzed reactions of allenols with 4‐substituted‐1‐sulfonyl‐1,2,3‐triazoles has been achieved through the replacement of the 4‐aryl substituent by a 4‐acetyl moiety.

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