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A Convenient Synthesis of Sulfones via Light Promoted Coupling of Sodium Sulfinates and Aryl Halides
Author(s) -
Chen Lei,
Liang Jie,
Chen Zhenyu,
Chen Jie,
Yan Ming,
Zhang Xuejing
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201801390
Subject(s) - chemistry , aryl , halide , photochemistry , catalysis , aryl radical , electron transfer , photocatalysis , photoredox catalysis , acceptor , combinatorial chemistry , organic chemistry , alkyl , physics , condensed matter physics
A convenient and ecient synthesis of sulfones from sulfinates and aryl halides was developed. The reaction occurred under UV irradiation without transition metal catalyst or photocatalyst. A radical pathway via single‐electron transfer (SET) of electron donor‐acceptor (EDA) complex was proposed based on UV‐vis spectroscopy, radical inhibiting and trapping experiments.
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