Visible‐Light‐Mediated Chlorosulfonylative Cyclizations of 1,6‐Enynes | Zendy

Hou Hong | Zendy; Li Hengxue | Zendy; Xu Yue | Zendy; Song Chuanqi | Zendy; Wang Chunling | Zendy; Shi Yaocheng | Zendy; Han Ying | Zendy; Yan Chaoguo | Zendy; Zhu Shaoqun | Zendy

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Visible‐Light‐Mediated Chlorosulfonylative Cyclizations of 1,6‐Enynes

Author(s) -

Hou Hong,

Li Hengxue,

Xu Yue,

Song Chuanqi,

Wang Chunling,

Shi Yaocheng,

Han Ying,

Yan Chaoguo,

Zhu Shaoqun

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201801157

Subject(s) - chemistry , sulfonyl , visible spectrum , photocatalysis , photochemistry , atom transfer radical polymerization , chlorine atom , combinatorial chemistry , chlorine , sulfone , organic chemistry , catalysis , medicinal chemistry , polymer , alkyl , physics , optoelectronics , copolymer

Described herein is a visible‐light‐mediated atom‐transfer radical cyclization (ATRC) using 1,6‐enynes as substrates. The sulfonyl chlorides not only served as sulfonyl radical sources but also provided a chlorine atom to enable the formation of highly functionalized cyclic products. This visible‐light‐mediated photocatalytic method is a mild and practical strategy for synthesizing chloroalkyl‐substituted cyclic alkenyl sulfones.

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