Stereospecific Al‐Catalysed Tandem  C−N / C−Se  Bond Formation of Isoselenocyanates with Aziridines: Synthesis and DFT Study | Zendy

Satheesh Vanaparthi | Zendy; Srivastava Hemant Kumar | Zendy; Kumar Sundaravel Vivek | Zendy; Sengoden Mani | Zendy; Punniyamurthy Tharmalingam | Zendy

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Stereospecific Al‐Catalysed Tandem C−N / C−Se Bond Formation of Isoselenocyanates with Aziridines: Synthesis and DFT Study

Author(s) -

Satheesh Vanaparthi,

Srivastava Hemant Kumar,

Kumar Sundaravel Vivek,

Sengoden Mani,

Punniyamurthy Tharmalingam

Publication year - 2019

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201801116

Subject(s) - chemistry , stereospecificity , tandem , substrate (aquarium) , stereochemistry , catalysis , cascade reaction , selectivity , scope (computer science) , combinatorial chemistry , computational chemistry , organic chemistry , materials science , oceanography , composite material , geology , computer science , programming language

Al‐catalyzed stereospecific tandem C−N / C−Se bond formation of chiral aziridines with isoselenocyanates is described with 90–99% ee and 77–91% yields. The mechanistic investigation using the computational study suggests that the reaction involves a concerted pathway (S N 2). The selectivity and substrate scope are the important practical features.

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